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糖类中间体 D-Glucose 衍生物及切块 (D-Glucose derivates and building blocks)

  • 关键字: D-Glucose-1 发布者:宣传部 发布时间:2012-09-24 16:09:51 点击数: 5244次

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Chemical name

Allyl 4,6-O-benzylidene-2-O-pivaloyl-3-O-tert-

butyldimethylsilyl-α-D-glucopyranoside

Product code

A0601

CAS No.

 

Formula

C27H42O7Si

FW

506.70

Physical state

Colorless syrup

mp (°C)

 

References

 

 

 

 

Chemical name

Allyl 4,6-O-benzylidene-3-O-tert-butyldimethylsilyl-α-D-

glucopyranoside

Product code

A0602

CAS No.

 

Formula

C22H34O6Si

FW

422.59

Physical state

Colorless syrup

mp (°C)

 

References

 

 

 

 

Chemical name

Methyl 1,2,3,4-tetra-O-acetyl-β-D-glucopyranuronate

Product code

A0603

CAS No.

7355-18-2

Formula

C15H20O11

FW

376.31

Physical state

Colorless crystal

mp (°C)

178

References

J. Am. Chem. Soc. 1955, 77, 3310

 

 

 

Chemical name

Methyl (ethyl 2,3,4-tri-O-acetyl-1-thio-β-D-glucopyranosyl)

uronate

Product code

A0604

CAS No.

 

Formula

C15H22O9S

FW

378.39

Physical state

Colorless solid

mp (°C)

108.5-109.5

References

Carbohydr. Res.1998, 308, 287

 

 

 

Chemical name

Methyl (ethyl 2,3,4-tri-O-benzoyl-1-thio-β-D-glucopyranosyl)

uronate

Product code

A0605

CAS No.

 

Formula

C30H28O9S

FW

564.60

Physical state

Colorless solid

mp (°C)

 

References

Synthesis 1990, 9, 1241

 

 

 

Chemical name

Ethyl 2,3,4,6-tetra-O-benzoyl-1-thio-β-D-glucopyranoside

Product code

A0606

CAS No.

 

Formula

C36H32O9S

FW

640.70

Physical state

Colorless solid

mp (°C)

 

References

J. Carbohydr. Chem. 1994, 13, 1159

 

 

 

 

Chemical name

Phenyl 2,3,4,6-tetra-O-acetyl-1-thio-β-D-glucopyranoside

Product code

A0607

CAS No.

23661-28-1

Formula

C20H24O9S

FW

440.46

Physical state

Colorless solid

mp (°C)

 

References

J. Chem. Soc. Chem. Commun. 1990, 3, 270

 

 

 

Chemical name

Phenyl 2,3,4,6-tetra-O-benzoyl-1-thio-β-D-glucopyranoside

Product code

A0608

CAS No.

 

Formula

C40H32O9S

FW

688.74

Physical state

Colorless solid

mp (°C)

 

References

Liebigs. Ann. 1995, 6, 949

 

 

 

Chemical name

Methyl (phenyl 2,3,4-tri-O-acetyl-1-thio-β-D-glucopyranosyl)

uronate

Product code

A0609

CAS No.

 

Formula

C19H22O9S

FW

426.44

Physical state

Colorless solid

mp (°C)

115-116

References

Carbohydr. Res. 1995, 279, 161

 

 

 

 

Chemical name

Methyl 6-O-tert-butyldimethylsilyl-α-D-glucopyranoside

Product code

A0610

CAS No.

 

Formula

C13H28O6Si

FW

308.44

Physical state

Colorless solid

mp (°C)

155-157

References

J. Org. Chem. 1996, 61, 7666

 

 

 

Chemical name

Methyl 2,3,6-tri-O-benzoyl-α-D-glucopyranoside

Product code

A0611

CAS No.

 

Formula

C28H26O9

FW

506.50

Physical state

Colorless solid

mp (°C)

126-128

References

J. Carbohydr. Chem. 1999, 18, 69

 

 

 

 

Chemical name

Methyl 2,3,4-tri-O-benzoyl-α-D-glucopyranoside

Product code

A0612

CAS No.

34234-44-1

Formula

C28H26O9

FW

506.50

Physical state

Colorless solid

mp (°C)

143

References

Chem. Lett. 1996, 1, 79

 

 

 

Chemical name

Methyl 2,3,4-tri-O-benzoyl-6-phenylthio-6-deoxy-α-D-

glucopyranoside

Product code

A0613

CAS No.

 

Formula

C34H30O8S

FW

598.66

Physical state

Colorless syrup

mp (°C)

 

References

 

 

 

 

Chemical name

Methyl(methyl 2,3,4-tri-O-benzoyl-α-D-glucopyranoside)

uranate

Product code

A0614

CAS No.

 

Formula

C29H26O10

FW

534.51

Physical state

Colorless solid

mp (°C)

 

References

Chem. Zvesti. 1974, 28, 820

 

 

 

Chemical name

Ethyl 2,3,4-tri-O-benzoyl-6-phenylthio-6-deoxy-1-thio-α-D-

glucopyranoside

Product code

A0615

CAS No.

 

Formula

C35H32O7S2

FW

628.75

Physical state

Colorless solid

mp (°C)

 

References

 

 

 

 

Chemical name

Methyl 2,3-di-O-acetyl-6-phenylthio-6-deoxy-α-D-

glucopyranoside

Product code

A0616

CAS No.

 

Formula

C17H22O7S

FW

370.42

Physical state

Colorless solid

mp (°C)

 

References

 

 

 

 

Chemical name

1,2,3,4,6-O-Penta-acetyl-β-D-glucopyranose

Product code

A0617

CAS No.

604-69-3

Formula

C16H22O11

FW

390.34

Physical state

White solid

mp (°C)

132

References

Methods. Carbohydr. Chem. 1963, 2, 211

 

 

 

Chemical name

1,2,4,6-O-Tetra-acetyl-α/β-D-glucopyranose

Product code

A0618

CAS No.

13996-89-9

Formula

C14H20O10

FW

348.30

Physical state

White solid

mp (°C)

128

References

Carbohydr. Res. 1992, 224, 111

 

 

 

Chemical name

1,2,3,4,6-O-Penta-benzoyl-α-D-glucopyranose

Product code

A0619

CAS No.

22415-91-4

Formula

C41H32O11

FW

700.69

Physical state

yellowish solid

mp (°C)

190

References

Methods. Carbohydr. Chem. 1963, 2, 235

 

 

 

Chemical name

2,3,4,6-O-Tetra-benzoyl-α-D-glucopyranose

Product code

A0620

CAS No.

66530-18-5

Formula

C34H28O10

FW

596.58

Physical state

yellowish solid

mp (°C)

118-120

References

Tetrahedron 1993, 49, 7301

 

 

 

Chemical name

1,2,3,4-O-Tetra-benzoyl-β-D-glucopyranose

Product code

A0621

CAS No.

 

Formula

C34H28O10

FW

596.58

Physical state

white solid

mp (°C)

179-181

References

 

 

 

 

Chemical name

2,3,4,6-Tetra-O-acetyl-D-glucopyranosyl 1-(N-phenyl)-2,2,2-

trifluoroacetimidate

Product code

A0622

CAS No.

 

Formula

C22H24F3NO10

FW

519.14

Physical state

淡黄色固体

mp (°C)

 

References

 

 

 

 

Chemical name

Methyl 2,3,4-tri-O-acetyl-1-bromo-1-deoxy-α-D-glucopyranosid uronate

Product code

A0623

CAS No.

 

Formula

C13H17BrO9

FW

396.01

Physical state

白色泡状固体

mp (°C)

 

References

 

 

 

 

Chemical name

Benzoyl 2,3-di-O-benzoyl-4,6-O-benzylidene-α/β-D-glucopyranoside

Product code

A0624

CAS No.

 

Formula

C34H28O9

FW

580.58

Physical state

 

mp (°C)

 

References

 

 

 

 

Chemical name

Benzoyl 2,3-di-O-benzoyl-4,6-di-tert-butyldimethylsiyl-D-glucopyranoside

Product code

A0625

CAS No.

 

Formula

C39H52O9Si2

FW

721.00

Physical state

无色糖浆

mp (°C)

 

References

 

 

 

 

Chemical name

Benzoyl 4-O-acetyl-2,3-di-O-benzoyl-6-tert-butyldimethylsiyl-D-glucopyranoside

Product code

A0626

CAS No.

 

Formula

C35H40O10Si

FW

648.77

Physical state

白色泡状固体

mp (°C)

 

References

 

 

 

 

Chemical name

Methyl 4-O-acetyl-1,2,3-tri-O-benzoyl-D-glucopyranosid uronate

Product code

A0627

CAS No.

 

Formula

C30H26O11

FW

562.52

Physical state

白色泡状固体

mp (°C)

 

References

 

 

 

 

Chemical name

Methyl 4-O-acetyl-2,3-di-O-benzoyl-1-bromo-α-D-glucopyranosid uronate

Product code

A0628

CAS No.

 

Formula

C23H21BrO9

FW

521.31

Physical state

白色泡状固体

mp (°C)

 

References

 

 

 

 

Chemical name

1,5-Anhydro-3,4,6-tri-O-acetyl-2-deoxyl-D-arabino-hex-1-entitol (3,4,6-Tri-O-acetyl-D -glucal)

Product code

A0629

CAS No.

 

Formula

C12H16O7

FW

272.25

Physical state

无色糖浆

mp (°C)

 

References

 

 

 

 

Chemical name

3,4,6-Tri-O-acetyl-2-azido-2-deoxy-α/β-D-glucopyranosyl nitrate

Product code

A0630

CAS No.

 

Formula

C12H16N4O10

FW

376.28

Physical state

淡黄色糖浆

mp (°C)

 

References

 

 

 

 

Chemical name

tert-Butyldimethylsiyl-2-azido-2-deoxy-4,6-O-(4-methoxybenzylidene)-β-D-gluco -pyranoside

Product code

A0631

CAS No.

 

Formula

C20H31N3O6Si

FW

437.56

Physical state

淡黄色糖浆

mp (°C)

 

References

 

 

 

 

Chemical name

tert-Butyldimethylsiyl-2-azido-3-O-benzoyl-2-deoxy-4,6-O-(4-methoxybenzylidene) -β-D-glucopyranoside

Product code

A0632

CAS No.

 

Formula

C27H35N3O7Si

FW

541.67

Physical state

无色糖浆

mp (°C)

 

References

 

 

 

 

Chemical name

tert-Butyldimethylsiyl-2-azido-3-O-benzoyl-2-deoxy-6-O-(4-methoxybenzyl)-β-D-gluco -pyranoside

Product code

A0633

CAS No.

 

Formula

C27H37N3O7Si

FW

543.68

Physical state

无色糖浆

mp (°C)

 

References

 

 

 

 

Chemical name

tert-Butyldimethylsiyl-4-O-acetyl-2-azido-3-O-benzoyl-2-deoxy-6-O-(4-methoxybenzyl) -β-D-glucopyranoside

Product code

A0634

CAS No.

 

Formula

C29H39N3O8Si

FW

585.72

Physical state

无色糖浆

mp (°C)

 

References

 

 

 

 

Chemical name

4-O-Acetyl-2-azido-3-O-benzoyl-2-deoxy-6-O-(4-methoxybenzyl)-D-glucopyranose

Product code

A0635

CAS No.

 

Formula

C23H25N3O8

FW

471.46

Physical state

白色泡状固体

mp (°C)

 

References

 

 

 

 

Chemical name

4-O-Acetyl-2-azido-3-O-benzoyl-2-deoxy-6-O-(4-methoxybenzyl)-α/β-D-glucopyranosyl trichloracetimidate

Product code

A0636

CAS No.

 

Formula

C25H25Cl3N4O8

FW

615.85

Physical state

白色泡状固体

mp (°C)

 

References

 

 

 

 

Chemical name

3,4,6-Tri-O-acetyl-2-azido-2-deoxy-D-glucopyranose

Product code

A0637

CAS No.

 

Formula

C12H17N3O8

FW

331.28

Physical state

白色泡状固体

mp (°C)

 

References

 

 

 

 

Chemical name

3,4,6-Tri-O-acetyl-2-azido-2-deoxy-α/β-D-glucopyranosyl trichloracetimidate

Product code

A0638

CAS No.

 

Formula

C14H17Cl3N4O8

FW

475.67

Physical state

白色泡状固体

mp (°C)

 

References

 

 

 

 

Chemical name

2-Propynyl 2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside

Product code

A0639

CAS No.

 

Formula

C17H22O10

FW

386.35

Physical state

白色晶状固体

mp (°C)

 

References

 

 

 

 

Chemical name

2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl azide

Product code

A0640

CAS No.

 

Formula

C14H19N3O9

FW

373.32

Physical state

白色固体

mp (°C)

 

References

 

 

 

 

Chemical name

1,2-O-Isopropylidene-3-O-methyl-α-D-glucofuranose

Product code

A0641

CAS No.

 

Formula

C10H18O6

FW

234.25

Physical state

 

mp (°C)

 

References

 

 

 

 

Chemical name

Allyl D-glucopyranoside

Product code

A0642

CAS No.

 

Formula

7464-56-4

FW

C9H16O6

Physical state

220.22

mp (°C)

Yellowish syrup

References

α: 101.5, β: 101.5

 

 

 

Chemical name

Allyl 2,3,4,6-Tetra-O-benzoyl-α-D-glucopyranoside

Product code

A0643

CAS No.

 

Formula

C37H32O10

FW

636.64

Physical state

Colorless syrup

mp (°C)

 

References

 

 

 

 

Chemical name

Allyl 4,6-O-benzylidine-β-D-glucopyranoside

Product code

A0644

CAS No.

84276-56-2

Formula

C16H20O6

FW

308.33

Physical state

crystal

mp (°C)

144

References

 

 

 

 

Chemical name

2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl bromide

Product code

A0645

CAS No.

 

Formula

C14H19BrO9

FW

411.20

Physical state

白色固体

mp (°C)

 

References

 

 

 

 

Chemical name

1,6-anhydro-2-azido-2-deoxy-β-D-glucopyranose

Product code

A0646

CAS No.

 

Formula

C6H9N3O4

FW

187.15

Physical state

淡黄色固体

mp (°C)

 

References

 

 

 

 

Chemical name

1,6-anhydro-2-azido-3,4-di-O-benzyl-2-deoxy-β-D-glucopyranose

Product code

A0647

CAS No.

 

Formula

C20H21N3O4

FW

367.40

Physical state

黄色糖浆

mp (°C)

 

References

 

 

 

 

Chemical name

6-O-Acetyl-2-azido-3,4-di-O-benzyl-2-deoxy-α/β-D-glucopyranose

Product code

A0648

CAS No.

 

Formula

C22H25N3O6

FW

427.45

Physical state

 

mp (°C)

 

References

 

 

 

 

Chemical name

1,6-anhydro-2-azido-3-O-benzyl-2-deoxy-β-D-glucopyranose

Product code

A0649

CAS No.

 

Formula

C13H15N3O4

FW

277.28

Physical state

黄色固体

mp (°C)

 

References

 

 

 

 

Chemical name

1,2:5,6-Di-O-isopropylidene-α-D-glucofuranose

Product code

A0650

CAS No.

 

Formula

C12H20O6

FW

260.28

Physical state

白色针状晶体

mp (°C)

 

References

 

 

 

 

Chemical name

3-O-benzyl-1,2;5,6-di-O-isopropylidene-α-D-glucofuranose

Product code

A0651

CAS No.

 

Formula

C19H26O6

FW

350.41

Physical state

浅黄色粘稠液体

mp (°C)

 

References

 

 

 

Chemical name

3-O-Benzyl-1,2-O-isopropylidene-5,6-bis-O-mesyl-α- D-glucofuranose

Product code

A0652

CAS No.

 

Formula

C18H26O10S2

FW

466.52

Physical state

白色晶体

mp (°C)

 

References

 

 

 

 

Chemical name

Methyl 4,6-O-benzylidene-a-D-glucopyranose

Product code

A0653

CAS No.

 

Formula

C14H18O6

FW

282.29

Physical state

 

mp (°C)

 

References

 

 

 

 

Chemical name

Phenyl 1-thio-β-D-glucopyranose

Product code

A0654

CAS No.

 

Formula

C12H16O5S

FW

272.32

Physical state

白色固体

mp (°C)

 

References

 

 

 

 

Chemical name

Phenyl 2,3-di-O-benzyl-4,6-O-benzylidene-1-thio-β-D-glucopyranose

Product code

A0655

CAS No.

 

Formula

C33H32O5S

FW

540.67

Physical state

 

mp (°C)

 

References

 

 

 

 

Chemical name

Benzoyl 2,3-di-O-benzoyl-α/β-D-glucopyranoside

Product code

A0656

CAS No.

 

Formula

C27H24O9

FW

492.47

Physical state

白色泡状固体

mp (°C)

 

References

 

 

 

 

Chemical name

1,2,3,4- Tetra-O-acetyl-α/β-D-glucopyranoside

Product code

A0657

CAS No.

13100-46-4

Formula

C14H20O10

FW

348.30

Physical state

Colorless syrup

mp (°C)

 

References

 

 

 

 

Chemical name

Allyl 2,3-di-O-acetyl-6-O-pivaloyl-α-D-glucopyranoside

Product code

A0658

CAS No.

 

Formula

C18H28O9

FW

388.41

Physical state

Colorless syrup

mp (°C)

 

References

 

 

 

 

Chemical name

Allyl 3,4,6-tri-O-acetyl-α-D-glucopyranoside

Product code

A0659

CAS No.

 

Formula

C15H22O9

FW

346.33

Physical state

Colorless syrup

mp (°C)

 

References

 

 

 

 

Chemical name

Benzyl 3,4,6-tri-O-acetyl-β-D-glucopyranoside

Product code

A0660

CAS No.

53691-39-7

Formula

C19H24O9

FW

396.39

Physical state

Colorless syrup

mp (°C)

 

References

 

 

 

 

Chemical name

Isopropyl thyl 3,4,6-tri-O-acetyl-β-D-glucopyranoside

Product code

A0661

CAS No.

 

Formula

C15H24O9

FW

348.35

Physical state

Yellow syrup

mp (°C)

 

References

 

 

 

 

Chemical name

Ethyl 4,6-O-benzylidene-2,3-O-di-acetyl-1-thio-β-D- glucopyranoside

Product code

A0662

CAS No.

 

Formula

C19H24O7S

FW

396.45

Physical state

Colorless crystal

mp (°C)

139-141

References

 

 

 

 

Chemical name

Allyl 4,6-O-benzylidene-2,3-O-di-acetyl-β-D- glucopyranoside

Product code

A0663

CAS No.

 

Formula

C20H24O8

FW

392.40

Physical state

Colorless crystal

mp (°C)

187-189

References

 

 

 

 

Chemical name

Allyl 3-O-acetyl-2-O-(p-methoxybenzyl)-4,6-O-

benzylidene-α-D-glucopyranoside

Product code

A0664

CAS No.

 

Formula

C26H30O8

FW

470.51

Physical state

Colorless crystal

mp (°C)

136-138

References

 

 

 

 

Chemical name

Allyl 3-O-acetyl-α-D-glucopyranoside

Product code

A0665

CAS No.

 

Formula

C11H18O7

FW

262.26

Physical state

Colorless oil

mp (°C)

 

References

 

 

 

 

Chemical name

Allyl 3-O-acetyl-4,6-O-benzylidene-α-D-glucopyranoside

Product code

A0666

CAS No.

 

Formula

C18H22O7

FW

350.36

Physical state

Colorless crystal

mp (°C)

152-153.5

References

 

 

 

 

Chemical name

Allyl 2-O-acetyl-α-D-glucopyranoside

Product code

A0667

CAS No.

 

Formula

C11H18O7

FW

262.26

Physical state

Colorless syrup

mp (°C)

 

References

 

 

 

 

Chemical name

 

Product code

A0668

CAS No.

126777-64-8

Formula

C13H20O8

FW

304.29

Physical state

Colorless oil

mp (°C)

 

References

Carbohydr. Res. 1992, 237, 57

 

 

 

Chemical name

Methyl 2,3-di-O-benzyl-α-D-glucopyranoside

Product code

A0669

CAS No.

17791-36-5

Formula

C21H26O6

FW

374.43

Physical state

Colorless solid

mp (°C)

79-80

References

J. Chem. Soc. 1940, 453

 

 

 

Chemical name

2,3,4,6-Tetra-O-benzoyl-D-glucopyranosyl 1-(N-phenyl)-2,2,2-

trifluoroacetimidate

Product code

A0670

CAS No.

 

Formula

C42H32F3NO10

FW

767.20

Physical state

 

mp (°C)

 

References

 

 

 

 

Chemical name

Allyl  4,6-O-benzylidene-a-D-glucopyranoside

Product code

A0671

CAS No.

 

Formula

C15H18O6

FW

294.11

Physical state

 

mp (°C)

 

References

 

 

 

 

Chemical name

3-O-Benzyl-1, 2-O-isopropylidene-α-D-glucofuranose

Product code

A0672

CAS No.

 

Formula

C16H22O6

FW

310.14

Physical state

无色糖浆

mp (°C)

 

References

 

 

 

 

Chemical name

3-O-Benzyl-α/β-D-glucopyranose

Product code

A0673

CAS No.

 

Formula

C13H18O6

FW

270.11

Physical state

 

mp (°C)

 

References

 

 

 

 

Chemical name

2-Azido-2-deoxy-α-D-glucopyranose

Product code

A0674

CAS No.

 

Formula

C6H11N3O5

FW

205.07

Physical state

 

mp (°C)

 

References

 

 

 

 

Chemical name

Allyl 4,6-O-benzylidene-2-O-pivaloyl-α-D-glucopyranoside

Product code

A0675

CAS No.

 

Formula

C21H28O7

FW

392.44

Physical state

Colorless syrup

mp (°C)

 

References