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1

Synthesis of a key intermediate for corossolin using Hydrolytic kinetic resolution of epoxides

Chem. Commun.

11

2

Radical-Mediated Diastereoselective Construction of a Chiral Synthon for Synthesis of

Org.Lett.

757-759

5

3

Radical-Mediated Construction of Cyclopentane with Concurrent Formation of a Well-Defined Quaternary Center

J. Org.Chem.

7

4

Highly Efficient Glycosylation of Sapogenins

J. Org.Chem.

6

5

BOMI

Tetrahedron

3

6

Diastereoselective synthesis of 2,4,5-trisubs- tituted piperidines from enantiopure b- amino esters

D. Ma, H. Sun

Tetrahedron Lett.

6

7

Enantioselective syntheses of a-substituted glutamic acids and a,g-disubstituted glutamic acids by an asym-metric Strecker reaction

D. Ma, G. Tang,H. Tian, G. Zou

Tetrahedron Lett.

4

8

A Novel thiazolium type peptide coupling reagent for hindered amino acids

Tetrahedron

7

9

Synthesis of a group of diosgenyl saponins by a one-pot sequential glycosylation

B. Yu, H. Yu,

Tetrahedron Lett.

8

10

Synthesis of (2S,3R,4E,8E)-9-methyl-4,8- sphin- gadienine via a novel S_N2’ type reaction medi- ated by a thioether carbanion

Tetrahadron Lett.

1

11

Enantioselective synthesis of functionalized a- amino acids via a chiral guanidine catalyzed Michael addition reaction

D. Ma,

Tetrahedron: Asymmetry

24

12

Trichloroacetimidate as an efficient Protec-tive Group for Alcohols.

B. Yu, H. Yu,

Synlett

3

13

First examples of Friedel-Crafts alkylation using ketals as alkylating agents:an expeditious access to the benzenefused 8-oxabicyclo[3.2.1] octane ring system

J. Chem.Soc.

14

D. Ma, J.Zhang,

J. Chem. Soc.Perkin Trans.1

1703-1707

3

15

5-(1H-Benzotriazol-1-yloxy)-3,4-dihydro-1-methyl 2H-Pyrrolium Hexachloroantimonate(BDMP):A Highly Efficient Immonium Type Peptide Coupling Reagent

Chem.Lett.

16

Synthesis of three diosgenyl saponins: dioscin, polyphyllin D, and balanitin 7

Carbohydr. Res.

9

17

An efficient approach to the synthesis of ethyl esters of 2,6-anhydro-3-deoxy-D-Gluco and D-allo-heptanoates

J.Carbohydr. Chem.

1067-1077

4

18

Chemical Synthesis of Several 2'-O-,3'-O-Glyco- sylated Diosgenyl b-D-Glucopyranosides

J. Carbohydrate Chemistry

3

19

Total Synthesis of Cyclosporin O (CsO) both in Solution and Solid Phase Using Novel Thiazo- lium, Immonium and Pyridinium Type Coupling Reagents: BEMT, BDMP and BEP

J. Org.Chem.

9

20

General and Efficient Syntheses of C18-4,8- Sphingadienines via SN2’ Type Homoallylic Coupling Reactions Mediated by Thioether- Stabilized Copper Reagents

J. Org.Chem.

2

21

Total Synthesis of Fully Acetylated N-Acetyl- neuraminic Acid (Neu5Ac),2-Deoxy-

Org.Lett.

8

22

A Simple and Stereospecific Route to 2,6- Disubstituted 4-Hydroxypiperidines.Syn-thesis ofDendrobate Alkaloid (+)-241D and Formal Syn-thesis of (-)-Indolizidine 167B

D. Ma,H. Sun

Org.Lett.

15

23

Synthesis of Enantiopure

D. Ma,K. Ding

Org.Lett.

6

24

Application of asymmetric aminohydroxy-lation to heteroaromatic acrylates

Tetrahedron:
Asymmetry

4

25

Stereocontrolled Cyclopropanation of

D. Ma,Y. Jiang

Tetrahedron:
Asymmetry

3

26

A high-yielding low-cost facile synthesis of

Y. Wu

Tetrahedron:

Asymmetry

5

27

Enantioselective Synthesisof Ethyl 4,5,7,8,9-

Helv. Chim.

Acta.

1

28

HOBt and HOAt-derived immonium salts: new and highly efficient coupling reagents for peptide synthesis

Tetrahedron Lett.

4

29

Total synthesis of (2S,3S,4R)-plakoridine A

D. Ma,H. Sun

Tetrahedron
Lett.

6

30

A novel and expeditious approach to the stereoselective synthesis of 2-S-ethyl(phenyl)-2- deoxy-b-glycosides, ready precursors to 2-deoxy- b-glycosides

B. Yu,Z. Yang

Tetrahedron

Lett.

3

31

First Stereoselective Synthesis of the Versa-tile Chiral Building Block (7aR)-5,6-Dihydro-7a-methyl- 1H-indene-2,7(4H,7aH)-dione

Synthesis

2

32

New and Highly Efficient Immonium Type Peptide Coupling Reagents: Synthesis, Mecha- nism and Application

Tetrahedron

3

33

1-Ethyl 2-Halopyridinium Salts, Highly Effi- cient Coupling Reagents for Hindered Peptide Synthesis both in Solution and the Solid-Phase

Tetrahedron

5

34

Highly Efficient Synthesis of Sterically Hin- dered Peptides Containing N-Methylated Amino Acid Residues using a Novel 1H-Benzimidazo- lium Salt

Tetrahedron

2

35

Synthesis of a group of diosgenyl saponins with combined use of glycosyl trichloroacetimi-date and thioglycoside donors

J. Chem. Soc.,Perkin Trans.1

6

36

(1h-Benzotriazol-1-yloxy)-N,N-dimehylme-thaninium hexachloroantimonate (BOMI), a novel coupling reagent for solution and Solid-phase peptide synthsis

J. Pepide Res

37

Base-Catalyzed Epimeization of the Buteno-lide in Annonaccous Acetogenins

Chirality

1

38

Synthesis of (25R)-ruscogenin-1-yl b-D-xylo-

Carbohydr.

Res.

39

Rearrangement of sugar 1,2-orthoesters to glyco- sidic products: a mechanistic implication

Carbohydr.

Res.

1

40

Enantioselective Syntheses of Monotetrahydro- furan Annonaceous Acetogenins Tonkinecin and Annonacin Starting from Carbohydrates

　J. Org.

12

41

A New Reagent System for Modified Ullmann Type Coupling Reactions:NiCl₂(PPh₃)/PPh₃/Zn/NaH/Toluene

G. Lin,

J. Org.Chem.

　9

42

Stereoselective Synthesis of 2-S-Phenyl-2-deoxy-

B. Yu,Z. Yang

Org.Lett.

3

43

CuI-catalyzed Coupling Reaction of

D.Ma,C. Xia

Org.Lett.

6

44

Two-Component Method to Enantiopure

D. Ma,W. Zhu

Org.Lett.

7

45

Synthesis of enantiopure N-protected 4,5-disub- stituted 3-pyrrolidinones and N-protected 2,5- disubstituted 3-pyrrolidinones via the Dieckmann reaction of dicarbonyl compounds derived from enantiopure b-amino esters

Tetrahedron: Asymmetry

46

Nickel-catalyzed Ullmann-type Coupling Reaction to Prepare Tetra-ortho-substituted Biaryls

Synlett

5

47

Tandem Hemiketal Formation-Intramolecular Friedel-Crafts Alkylation: A Facile Route to Hetero-Atom-Substituted Benzo-Fused Bicyclo- [3.3.1]nonanes

Y.Wu,Y. Li#,Y. Wu

Helv.Chim. Acta

48

An Expeditious Access to Enantiomerically Pure cis-Dialkyl-Substituted

Y. Wu, X. Shen

Helv.Chim. Acta

2

49

The first synthetic route to furostan saponins

B. Yu, J. Liao,J. Zhang, Y.Hui

Tetrahedron

Lett.

6

50

Glycosyl trifluoroacetimidates. Part 1: Prepa- ration and application as new glycosyl donors

B. Yu,H. Tao

Tetrahedron
Lett.

8

51

Solid-phase synthesis of peptide aldehydes directly on acetal resin

Tetrahedron
Lett.

3

52

A stereospecific synthesis of L-ribose and L-ribo- sides from D-galactose

Tetrahedron
Lett.

3

53

Synthesis of N-Boc and N-Fmoc dipeptoids with nucleobase residues as peptoid nucleic acid monomers

Tetrahedron

1

54

Asymmetric synthesis of a,a-disubstituted amino acids by diastereoselective functionalization of enantiopure phenyloxazinones, derivatives of asymmetric Streecker reaction products of aldehydes

Tetrahedron

3

55

Synthesis of chiral peptide nucleic acids using Fmoc chemistry

Tetrahedron

1

56

6-S-Phenyl-glycopyranosides as ready precursors to the synthesis of glycuronides

B. Yu, X. Zhu,Y. Hui

Tetrahedron

1

57

The X-ray structures of HOBt-based immoniumtype coupling reagents and the rearrangement of benzotriazolyl esters of N_a-protected amino acids or peptides: N-vs, O-substituted forms

J.Chem.Soc.,
Perkin Trans.2

58

The development of highly efficient onium-type peptide coupling reagents based upon rational molecular design

J. Peptide

Res.

59

An improved synthesis of the saponin, polyphyllin D

Carbohydr.

Res.

4

60

Stereoselective synthesis of 2-S-ethyl(phenyl)-2-

Carbohydr.

Res.

61

Glycosyl trifluoroacetimidates. 2. Synthesis of dioscin and xiebai saponin I.

B. Yu,H. Tao

J. Org.Chem.

2

62

A New Synthesis of Neu5Ac from D-Glucono- d - lactone

J. Org.Chem.

2

63

Synthesis of Natural Fragrant Molecules cis-3- Methyl-4-Decanolide and Aerangis Lactone. General Enantioselective Routes to b ,g -cis-Disubstituted g -Lactones and g , d -cis-Disub- stituted d - Lactones

Y. Wu, X. Shen,C.Tang, Z.Chen,Q. Hu, W. Shi

J. Org.Chem.

3

64

Nickel-Catalyzed Tandem Reaction to Asymmetric Synthesis of Chiral Phthalides

Synlett.

65

Synthesis of quercetin 3-O-(2”-galloyl)-a-L-ara- binopyranoside

Tetrahedron
Lett.

1

66

A short synthesis of the HIV-protease inhi-bitor nelfinavir via a diastereoselective addition of ammonia to the? a,

D. Ma, B. Zou,W. Zhu, H. Xu

Tetrahedron

Lett.

67

Regioselective acylation at the 5- or 6-position of L-tryptophan derivatives

Tetrahedron

Lett.

68

Preferential Hydrolysis of Benzylic/Allylic Dithianes and Dithiolanes using o-iodoxybenzoic Acid (IBX) in DMSO

Y. Wu,X.Shen,

Tetrahedron

Lett.

2

69

A stereospecific synthesis of L-deoxyribose, L-ribose and L-ribosides

Tetrahedron

1

70

Synthesis of 3-deoxy-2-ulosonic acid KOD and 4- epi-KDN,a highly efficient approach of 3-C homologation by propargylation and oxidation

Tetrahedron

71

An efficient method for the synthesis of a -keto acid esters from terminal alkynes

Tetrahedron

Lett.

72

Efficient formal synthesis of dendrobatid alkaloid indolizidine (-)-209B

D. Ma,X. Pu, J. Wang

Tetrahedron:
Asymmetry

2

73

Amino alcohols with the bicyclo [3.3.0] octane scaffold as ligands for the catalytic enan- tioselective addition of diethylzinc to aldehydes

Tetrahedron:

1

74

Synthesis of Enantiopure Substituted Dihydro-

Tetrahedron:

75

A straight forward synthesis of DAH (3-deoxy- D-arabino-hept-2-ulosonic acid) and DRH (3-de- oxy-D-ribo-hept-2-ulosonic acid)

J. Chem.

76

Acid catalysed rearrangement of a spiroketal enol ether. An easy synthesis of chrycorin

J. Chem.

77

Straightforward Synthesis of Two Pairs of nantiomeric Butenolides 3-Tetradecyl- and 3-He- xa-decyl-5-methyl-2(5H)-furanone

Enantiomer

78

A Facile Synthesis of cis-1-Methyl-1,2,3,3a, 4,8b-hexahydropyrrolo[3,2-f]pyrindine, an Annu- lated Nicotine Analog

H. Zhai, P. Liu,S. Luo, F. Fang,M. Zhao

Org.Lett

2

79

Facile Cleavage of Triethylsilyl (TES) Ethers Using ortho-Iodoxybenzoic Acid (IBX) without Affecting tert-Butyldimethylsilyl (TBS) Ethers

Y. Wu, J. Huang,X.Shen, Q. Hu,C. Tang, L. Li

Org.Lett.

2

80

A mild method for Ullmann coupling reaction of amines and aryl halides

D. Ma, Q. Cai,H. Zhang

Org.Lett.

3

81

N,N-Dimethyl Glycine Promoted Ullmann Coupling Reaction of Phenols and Aryl Halides

D. Ma,Q.Cai

Org.Lett.

1

82

Efficient sialylation with phenyltrifluoroaceti-

Org.Lett.

83

Preparation of syn-

Org. Lett.

84

Synthesis of a New Stable Conformationally Constrained 2,7-Anhydrosialic Acid Derivative.

J. Org.Chem.

85

Asymmetric Total Synthesis of (-)-Alkaloid 223A and its 6-Epimer

J. Org. Chem.

86

Total synthesis of the antiallergic naph- tho-alpha-pyrone tetraglucoside, cassiaside C2, isolated from cassia seeds

J. Org.

Chem.

87

1-2 Migration and concurrent glycosidation of phenyl 1-thio-mannopyranosides via 2,3-O-cyclic dioxonium intermediates

Tetrahedron

88

A Practical Procedure for the Multisubstituted β-Naphthols and their Derivatives

Tetrahedron

89

Asymmetric dihydroxylation of heteroaromatic acrylates

Tetrahedron Letters

1

90

Stereospecfic route to enantiopure all cis-2,3,6-

D.Ma,N. Ma

Tetrahedron Lett.

1

91

Carbohydrates as Chiral Auxiliaries in Enantio-

Tetrahedron Lett.

92

A new mild regioselective bromination of arylamines

Tetrahedron Lett.

93

Recent Progress in Syntheses of Higher 3-Deoxy-2- ulosonic Acids and Their Derivatives

Current Org. Chem.

94

Asymmetric synthesis of (-)-deoxoprosophylline

Tetrahedron: Asymmetry

1

95

Synthesis of a typical N-acetylglucosamine containing saponin, Oleanolic acid 3-O-alpha- L- arabinopyranosyl-(1-2)-alpha-L-arabinopyra-nosyl-(1-6)-2-acetamido-2-deoxy-beta-D-glucopyranoside

Carbohydr. Res.

96

Synthesis of 3-substituted pyrrole derivatives with oligo(ethylene glycol) chains

Heterocyles